Pressure and temperature dependence of the viscosity of a NaAlSi<Subscript>2</Subscript>O<Subscript>6</Subscript> melt

The viscosity of a silicate melt of composition NaAlSi₂O₆ was measured at pressures from 1.6 to 5.5 GPa and at temperatures from 1,350 to 1,880°C. We employed in situ falling sphere viscometry using X-ray radiography. We found that the viscosity of the NaAlSi₂O₆ melt decreased with increasing pressure up to 2 GPa. The pressure dependence of viscosity is diminished above 2 GPa. By using the relationship between the logarithm of viscosity and the reciprocal temperature, the activation energies for viscous flow were calculated to be 3.7 ± 0.4 × 10² and 3.7 ± 0.5 × 10² kJ/mol at 2.2 and 2.9 GPa, respectively.     

Gas seepage from Tokamachi mud volcanoes, onshore Niigata Basin (Japan): Origin, post-genetic alterations and CH4-CO2 fluxes

Methane and CO₂ emissions from the two most active mud volcanoes in central Japan, Murono and Kamou (Tokamachi City, Niigata Basin), were measured in from both craters or vents (macro-seepage) and invisible exhalation from the soil (mini- and microseepage). Molecular and isotopic compositions of the released gases were also determined. Gas is thermogenic (δ¹³C_CH4 from −32.9‰ to −36.2‰), likely associated with oil, and enrichments of ¹³C in CO₂ (δ¹³C_CO2 up to +28.3‰) and propane (δ¹³C_C3H8 up to −8.6‰) suggest subsurface petroleum biodegradation. Gas source and post-genetic alteration processes did not change from 2004 to 2010. Methane flux ranged within the orders of magnitude of 10¹-10⁴ g m⁻² d⁻¹ in macro-seeps, and up to 446 g m⁻² d⁻¹ from diffuse seepage. Positive CH₄ fluxes from dry soil were widespread throughout the investigated areas. Total CH₄ emission from Murono and Kamou were estimated to be at least 20 and 3.7 ton a⁻¹, respectively, of which more than half was from invisible seepage surrounding the mud volcano vents. At the macro-seeps, CO₂ fluxes were directly proportional to CH₄ fluxes, and the volumetric ratios between CH₄ flux and CO₂ flux were similar to the compositional CH₄/CO₂ volume ratio. Macro-seep flux data, in addition to those of other 13 mud volcanoes, supported the hypothesis that molecular fractionation (increase of the “Bernard ratio” C₁/(C₂ + C₃)) is inversely proportional to gas migration fluxes. The CH₄ “emission factor” (total measured output divided by investigated seepage area) was similar to that derived in other mud volcanoes of the same size and activity. The updated global “emission-factor” data-set, now including 27 mud volcanoes from different countries, suggests that previous estimates of global CH₄ emission from mud volcanoes may be significantly underestimated.     

Carbon and oxygen isotope chemostratigraphies of the Yangtze platform,South China: Decoding temperature and environmental changes through the Ediacaran

Multicellular animals first appeared on the earth during the Ediacaran period. However, the relationship between the abrupt biological evolution and environmental changes is still ambiguous. In order to examine seawater temperature and the carbon cycle through the Ediacaran, we analyzed the carbon and oxygen isotope compositions of carbonate rocks from drill cores from the Three Gorges area, South China. Importantly, the core samples include the Nantuo tillite, corresponding to the Marinoan glaciation, through the Doushantuo to the lower Dengying Fms. in ascending order.The δ¹³C profile displays five positive and five negative anomalies (PI-1 to 5 and NI-1 to 5), and the oxygen isotopes display very high absolute values around 0‰ with the highest at + 1.83‰. The combined δ¹⁸O and δ¹³C chemostratigraphies display both positive and negative correlations between the δ¹⁸O and δ¹³C values. The occurrence of the negative correlations supports the preservation of primary δ¹⁸O and δ¹³C values.The sample NI-4 has a negative correlation of the δ¹⁸O and δ¹³C excursions. The correlation supports a primary signature for both δ¹⁸O and δ¹³C variations. The positive δ¹⁸O excursion, accompanied by evidence of a eustatic sea-level fall, provides direct evidence for global cooling in the mid-Ediacaran; the 580 Ma Gaskiers Glaciation is a potential candidate for this global cooling event. The negative δ¹³C excursion was possibly caused by an increase in remineralization of dissolved organic carbon (DOC) due to enhanced continental weathering during the glaciation.Sample NI-5 is characterized by very low δ¹³C values, down to ? 10‰, corresponding to the Shuram-Wonoka-Pertatataka Excursion. The cause of the δ¹³C negative excursion is still not clear. However, a ubiquitous occurrence in excursions worldwide, and the lower δ¹³C values in deeper sections favor the enhancement of remineralization and respiration rather than secondary alteration, a restricted sea environment and lithification in coastal areas.     

Prediction of ground motion in the Osaka sedimentary basin associated with the hypothetical Nankai earthquake

We studied the long-period ground motions in the Osaka sedimentary basin, Japan, which contains a 1- to 3-km thickness of sediments and is the site of many buildings or construction structures with long-natural period. We simulated the broadband ground motions likely to be produced by the hypothetical Nankai earthquake: the earthquake expected to give rise to the most severe long-period ground motion within the basin. For the simulation, we constructed multiscale heterogeneous source models based on the Central Disaster Management Council of Japan (CDMC) source model and adopted a hybrid computation method in which long-period motion and short-period motion are computed using a 3-D finite difference method and the stochastic Green’s function method, respectively. In computing long-period motions, we used a 3-D structure model of the crust and the Osaka sedimentary basin. The ground motions are estimated to have peak velocities of 50–90 cm/s, prolonged durations exceeding 300 s, and long predominant periods of 5–10 s in the area with great thickness of sediments. The predominant periods are in agreement with an approximate evaluation by 4 H/V _s where H and V _s are the thickness of the sediment and the average S wave velocity, respectively.     

Juxtaposition of India and Madagascar: A Perspective

Proterozoic terrains in South India and Madagascar provide important clues in understanding the Gondwanaland tectonics, especially the assembly of this mega-continent during the Pan-African period. The Archaean terrains in both Madagascar and India are characterized by N-S trending greenstone belts occurring within gneissose granitic rocks in the northern part. Extensive development of K-rich granitic rocks of ca. 2.5 Ga is also characteristic in both areas. Such a broad age zonation of younger Dharwar (ca 2.6–3.0 Ga) in the north and the older Sargur (ca 3.0–3.4 Ga) in the south as in South India remains to be identified in future studies from Madagascar. The occurrence of greenschist facies rocks in the northeastern part and higher grade rocks in most of other parts in the north-central terrain of Madagascar is comparable with the general tendency of increasing metamorphic grade from northwestern to southern areas ranging from greenschist to granulite facies in South India. The Proterozoic crystalline rocks in both continents show pronounced lithological similarity with the wide occurrence of graphite-bearing khondalite in association with charnockitic rocks. While the Archaean-Proterozoic boundary is well defined in southern India by the Palghat-Cauvery or the KKPT shear zones as recently identified, this boundary is ill-defined in Madagascar due to extensive Pan-African overprinting, as well as the development of the Proterozoic cover sequence, the Itremo Group. There is also a possible general correlation between the Mesoproterozoic cover sequences in Madagascar and India, such as between the Itremo Group of west-central Madagascar and the Kaladgi and Cuddapah sequences of South India. The Pan-African granulite facies metamorphism of ca. 0.5 Ga extensively developed in both India and Madagascar is generally comparable in intensity and extent. P-T conditions and P-T-t paths also appear comparable, with the general range of ca. 700–1000°C and 6–9 kb, and near-isothermal decompressional paths. A-type granite plutons and alkaline rocks including anorthosites and mafic plutonic rocks of ca. 500–800 Ma develop in both terrains, provide strong basis for the correlation of both terrains, and define a Pan-African igneous province within East Gondwanaland. Major shear zones in both continents are expected to play a critical role in the correlation, albeit are still poorly constrained. Detailed elucidation of the tectonic history of the shear zones, and the timing of various events along the shear zones would provide important constraints on the correlation of the two continental fragments.     

Clustering of galaxy clusters in cold dark matter universes

We use very large cosmological N -body simulations to obtain accurate predictions for the two-point correlations and power spectra of mass-limited samples of galaxy clusters. We consider two currently popular cold dark matter (CDM) cosmogonies, a critical density model ( τ CDM) and a flat low density model with a cosmological constant (ΛCDM). Our simulations each use 10⁹ particles to follow the mass distribution within cubes of side 2  h ⁻¹ Gpc ( τ CDM) and 3  h ⁻¹ Gpc (ΛCDM) with a force resolution better than 10⁻⁴ of the cube side. We investigate how the predicted cluster correlations increase for samples of increasing mass and decreasing abundance. Very similar behaviour is found in the two cases. The correlation length increases from     for samples with mean separation     to     for samples with     The lower value here corresponds to τ CDM and the upper to ΛCDM. The power spectra of these cluster samples are accurately parallel to those of the mass over more than a decade in scale. Both correlation lengths and power spectrum biases can be predicted to better than 10 per cent using the simple model of Sheth, Mo & Tormen. This prediction requires only the linear mass power spectrum and has no adjustable parameters. We compare our predictions with published results for the automated plate measurement (APM) cluster sample. The observed variation of correlation length with richness agrees well with the models, particularly for ΛCDM. The observed power spectrum (for a cluster sample of mean separation     ) lies significantly above the predictions of both models.